Material Technology

Simulation of solid-state growth of iron sulfides in sour corrosion conditions

Amri, J. , Kvarekvål, J. , Malik, B.
Corrosion 2011, Houston, Tex., 2011-03-12--03-17. Paper 11078
Publ. year
2011
Publ. type
paper
Abstract
In order to predict and understand general and localized corrosion attacks on carbon steels in sour service, fundamental understanding of the growth and breakdown mechanisms of iron sulfides is required. Based on the concept of “Conservative Ensembles”, a model for the solid-state growth mechanism of sulfur-deficient iron sulfide has been developed. The model enables numerical simulations of iron sulfide growth limited by multicomponent transport through the FeS layer using the phenomenological formalism of linear irreversible thermodynamics. ©NACE International. All rights reserved. Paper Number 11078 reproduced with permission from CORROSION 2011 Annual Conference and Exhibition, San Antonio, Texas. http://www.nace.org
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